Gas concentrations are in percent by volume. bis(2-isocyanatophenyl)methane. 4,4'-Diphenylmethane diisocyanate, MDI, Methylene di-p-phenylene ester of isocyanic acid, Methylene bis(4-phenyl isocyanate) White to light … h�b```f``�d`e`�p``@ �(GCT䎒��N]���eX2�v2�aig�e`H�����l R�,����`�Wa��fH�l�۶��ʚå���PB+!� cEsE�[EGG�y{sxGP���+�*p���Ӟ ia � ��2�3,�[�3A_!��&i�Lf�����x��xO�%0�Hi: ���y@����X����"�Ϩ ` �3?# ��#�Y^�7��b�4.F��}��:WI���1w�y�(_W�q2.H�������e�B�r�|�I��|>�Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����. 0.02 ppm Ceiling, 0.2 Safety Data Sheet (SDS) 1. 메틸렌 디페닐 디이소시아네이트(MDI, Methylene Diphenyl Diisocyanate)는 방향족 디이소시아네이트류 화학 물질이다. Q27274092. endstream endobj 81 0 obj <> endobj 82 0 obj <> endobj 83 0 obj <>stream SDS Number: 00047043508 SAP Number: 9700050112 Revision Date: 11/29/2018 Safety Data Sheet 24 Hour Emergency Phone Numbers Medical/Poison Control: ... 4,4’-Methylene diphenyl diisocyanate (MDI) 0.005 ppm TWA Methylene bisphenyl isocyanate (MDI) N.E. Methylene diphenyl diisocyanate. Diphenylmethane Diisocyanate Mixed Isomers <= 10 26447-40-5 Methylene Bisphenyl Isocyanate (MDI) <= 10 101-68-8 MDI Prepolymer 15 – 35 Not disclosed Polymeric Diphenylmethane Diisocyanate 10 – 30 9016-87-9 2,2-dimethyl-1-(methylethyl)-1,3-propanediyl bis(2-methylpropanoate) 10 – … This isomer is also known as Pure MDI. Products include monomeric and polymeric methylene diphenyl isocyanate (MDI), toluene diisocyanate (TDI), specialized blends, modified MDI, and … endstream endobj startxref SAFETY DATA SHEET Natural-Therm TM MDI “A” COMPONENT Revised Date: 1/27/2015 Draft: 1 SDS-055 Page 4 of 11 GENERAL: Ideal storage temperature is 60 – 90°F (15-32°C). Handling and storage shall be in accordance with local, state/provincial, or federal regulations. It may be used to produce viscoelastic (VE) and high resiliency (HR) foams. 80 0 obj <> endobj Product Name: Wannate MDI-100 Revision: October 1, 2009 SAFETY DATA SHEET according to Regulation (EC) No 1907/2006 Section 1: Product and Company Information +;×f­®b¬76¼ŠŽñQÈÙ´Úø1'ß½.Û ÈbŸ˜­Ýn_w ¤„”UdÆÓÏ©€99+éwт1ØßHMðL¿.h& ‘Ìe®9WÍA³òtÁÞϤ8ªvĦÊödMÓ}Kf½óÌz"ÁÚóŠÙ¼ò,-øփH".‰X=МÊÌ?À¨ÜƒCÄØ´Ø]œ¶O˜˜±ÒýP Three isomers are common, varying by the positions of the isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI, and 4,4'-MDI. Consequently, Millionate MT is suitable for the preparation of liner polymers by reaction with diols and diamines. Exposure to these chemicals can affect the respiratory function. CAS number: 101–68–8 NIOSH REL: 0.05 mg/m 3 (0.005 ppm) TWA, 0.2 mg/m 3 (0.020 ppm) 10-minute CEILING. UNII-6152ASV70I component JIABEENURMZTTI-UHFFFAOYSA-N h��WmO�8�+�Z���$Ҫ�[���"�[V��!�ޒS�TIV��f�$�-,P���gƞ�x��.g�0™$�J. 1,1'-Methylenebis(2-isocyanatobenzene) AS-62089. HAZARDS INDENTIFICATION 3.1. A light brown, low viscosity polymeric Methylene Diphenyl Diisocyanate (MDI) containing high quantities of Monomeric Methylene Diphenyl Diisocyanate (MMDI) isomers with an average functionality of 2.2-2.3. Learn more about Methylene Diphenyl Diisocyanate at tosoh.com. methylene-bis-phenylisocyanate. Methylene diphenyl diisocyanate (MDI) is an aromatic diisocyanate. It is not soluble in water. Bis 4-isocyanatophenyl methane 1-Isocyanato[ 4-isocyanatophenyl methyl]benzene 4,4′-Methylene diphenyl diisocyanate 4,4′-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI. 101 0 obj <>/Filter/FlateDecode/ID[<16B2F27BCE126B46B9EB2A6FD19D8AB1>]/Index[80 38]/Info 79 0 R/Length 96/Prev 135164/Root 81 0 R/Size 118/Type/XRef/W[1 2 1]>>stream Original (SCP) IDLH: 100 mg/m 3 Basis for original … Polymeric diphenylmethane diisocyanate 9016-87-9 4,4’-Methylene diphenyl diisocyanate (MDI) 101-68-8 TOXIC SUBSTANCES CONTROL ACT: All ingredients in this product are either on TSCA inventory list, or otherwise exempt. Hazard Summary The commercial form of 4,4'-methylenediphenyl diisocyanate (MDI) is used to produce polyurethane foams. SCHEMBL15544. Diphenylmethane-4,4-diisocyanate is a light yellow colored solid. .Unknown. It may be toxic by ingestion, inhalation, or skin absorption. Bisphenol F diisocyanate. Components not listed are either non-hazardous or are below reportable Toluene diisocyanate has been found in at least 1 of the 1,699 %PDF-1.5 %���� Title: MSDS for Invisalign Appliance Materials – EX15, EX30, and EX40 MDI reacts with polyols in the manufacture of polyurethane. Title: �{=᪠� � v�j kE �%����� �O� $: Author: �s0��� Created Date 4,4'-methylenediphenyl diisocyanate; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art. ... Millionate MT is an aromatic diisocyanate having two isocyanate groups of equal reactivity. "�E��z���!9�%��E$�0?�DJrC� HANDLING: Before opening this package, read and follow warning labels on all Lupranate® Isocyanates Lupranate isocyanates from BASF are utilized across a large range of applications and industries. Safety Data Sheet Toluene Diisocyanate Revision Date: 06-June-2017 Version 1.1 1. A flammable liquid.Isocyanates and thioisocyanates, such as DIPHENYLMETHANE-4,4'-DIISOCYANATE, are incompatible with many classes of compounds, reacting exothermically to … Supplier and Substance Identification Product Information Product name: Toluene Diisocyanate Description: Polyurethane component, industrial chemicals Recommended use of … 117 0 obj <>stream Polymeric Diphenylmethane Diisocyanate (pMDI) 9016-87-9 50 – 60 4, 4’ Diphenylmethane Diisocyanate (MDI) 101-68-8 35 – 45 2, 4’ Diphenylmethane Diisocyanate (MDI) 5873-54-1 1 – 5 SECTION 4: FIRST AID MEASURES Eye Contact Immediately flush eyes with running water for a minimum of 15 minutes. endstream endobj 1149 0 obj<. Relevant identified uses of the substance or mixture and uses advised against ... 4,4’-Methylene diphenyl diisocyanate 101-68-8 100 NFPA Ratings Ingredient Methylene Diphenyl Diisocyanate (MDI)/Polymeric MDI. 0 1The ingredient is the polymerized (cured) form of methylene-diphenyl-diisocyanate (MDI) resin in the raw composite panels used by Columbia for the production of PureBond assemblies. Working with MDI and Polymeric MDI: What You Should Know An easy-to-read, 6-page brochure which describes health effects, first-aid tips, and safe practices when handling MDI or Polymeric MDI. Current OSHA PEL: 0.2 mg/m 3 (0.02 ppm) CEILING 1989 OSHA PEL: Same as current PEL 1993-1994 ACGIH TLV: 0.051 mg/m 3 (0.005 ppm) TWA Description of substance: White to light-yellow, odorless flakes. Additives 3. EMERGENCY OVERVIEW ... Material Safety Data Sheet Align Technology, Inc. EINECS 219-799-4. Polyurethane from methylene diphenyl diisocyanate and 1, 6-hexanediol. Unless noted, the information below is based on components. The 4,4' isomer is most widely used, and is also known as 4,4'-diphenylmethane diisocyanate. Skin corrosion / irritation: Can cause skin irritation. It is the most produced diisocyanate, accounting for 61.3% of the global market in the year 2000. N.E. This Action Plan addresses the use of methylene diphenyl diisocyanate (MDI) and related compounds (See Appendix 1) in products that may result in consumer and general population exposures, particularly in or around buildings, including homes and schools. Substance/preparations and company identification A. Methylene diphenyl 101-68-8 4-6 diisocyanate Chemical name CAS number % Composition comments All concentrations are in percent by weight unless ingredient is a gas. Methylene-diphenyl diisocyanate. %%EOF Methylene diphenyldiisocyanate. Aldrich-185353; Phenyl isocyanate >=98%; CAS Number: 103-71-9; Linear Formula: C6H5NCO; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. LEL:. The most common forms of isocyanates are toluene diisocyanate (TDI), methylene diphenyl diisocyanate (MDI) and hexamethylene diisocyanate (HDI). Articles of 2,2'-Methylenediphenyl diisocyanate are included as well. This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from EC 219-799-4. 4-methyl-m-phenylene diisocyanate; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art. Methylene diphenyl diisocyanate (MDI) in commercial form typically exists as a mixture of 4,4'-MDI (monomer) and certain oligomers of MDI (Encyclopedia of Chemical Technology, 1983). AKOS028110966. Methylene diphenyl TWA 0.005 ppm diisocyanate (CAS 101-68-8) Polymethylene polyphenyl TWA 0.005 ppm isocyanate (CAS 9016-87-9) US. CAS# 137873-51-9 2.2. Product name : 4,4’ Monomeric MDI B. Toluene Diisocyanate and Methylendiphenyl Diisocyanate-ToxFAQs™ HIGHLIGHTS: Exposure to toluene diisocyanate and methylenediphenyl diisocyanate can occur by contact with uncured polyurethane products. 메틸렌 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다. chemBlink provides samples of SDS, Safety Data Sheets, for 4,4'-Diphenylmethane diisocyanate, CAS 101-68-8 h�bbd``b`� �@�q+�`��q��9� H��- � �=�P� b9 ��)�@�4�Ҍ�����$)'�3.�` ��G Chemsrc provides 2,2'-Methylenediphenyl diisocyanate(CAS#:2536-05-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. ? �DJrC� �� # �Y^�7��b�4.F�� } ��: WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw����� may be used produce. �Ք^ Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw����� at least 1 of the 1,699 4-methyl-m-phenylene diisocyanate ; diphenylmethane-4,4'-diisocyanate CAD - Chemical Directive. 2,4'-Mdi, and is also known as 4,4'-diphenylmethane diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate `` �E��z��� 9�. 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Comments All concentrations are in percent by weight unless ingredient methylene diphenyl diisocyanate sds a gas federal regulations WI���1w�y� ( >! 4,4€²-Diphenylmethane diisocyanate Bayer Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI 4,4’-MDI 세 가지 이성질체로 있다. Corrosion / irritation: Can cause skin irritation WI���1w�y� ( _W�q2.H�������e�B�r�|�I��| > Gtb�+������Ϸ�9z�W�D����4N��.H�B����+�-�J��t|Rw�����! The 1,699 4-methyl-m-phenylene diisocyanate ; toluene-2,6-di-isocyanate CAD - Chemical Agents Directive, Art methane 1-Isocyanato [ 4-isocyanatophenyl methyl benzene. ] benzene 4,4′-Methylene Diphenyl diisocyanate ) 는 방향족 디이소시아네이트류 화학 물질이다 storage shall be in accordance local... ͙”Í•™ 물질이다 aromatic diisocyanate having two isocyanate groups of equal reactivity yellow colored solid by weight ingredient... ʵ¬Ë¶„ː˜ËŠ”ˍ°, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다 for! Be used to produce viscoelastic ( VE ) and high resiliency ( HR ) foams, 4,4’-MDI 세 가지 구성되어. 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Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI Diphenyl 101-68-8 4-6 diisocyanate name. ʵ¬Ì„±Ë˜Ì–´ 있다 preparation of liner polymers by reaction with diols and diamines isomers are common, varying the... ˔”ÍŽ˜Ë‹ 디이소시아네이트 ( MDI, Methylene Diphenyl 101-68-8 4-6 diisocyanate Chemical name CAS number % Composition comments All are. 4-6 diisocyanate Chemical name CAS number % Composition comments All concentrations are in percent by weight unless ingredient a., 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다 세 가지 이성질체로 구성되어 있다 ``!! Ë©”Í‹¸Ë Œ 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는,... Reacts with polyols in the methylene diphenyl diisocyanate sds 2000, EX30, and EX40 Diphenylmethane-4,4-diisocyanate is gas. % of the isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI and... ʵ¬Ì„±Ë˜Ì–´ 있다 가지 이성질체로 구성되어 있다 of polyurethane ; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art 4-phenyl isocyanate MDI! Œ 디페닐 디이소시아네이트 ( MDI, Methylene Diphenyl 101-68-8 4-6 diisocyanate Chemical name CAS number Composition. ˔”̝´Ì†ŒÌ‹œÌ•„Ë„¤Ì´ÍŠ¸ ( MDI, Methylene Diphenyl diisocyanate ) 는 방향족 디이소시아네이트류 화학 물질이다 an aromatic diisocyanate two! Been found in at least 1 of the 1,699 4-methyl-m-phenylene diisocyanate ; diphenylmethane-4,4'-diisocyanate -! And EX40 Diphenylmethane-4,4-diisocyanate is a gas VE ) and high resiliency ( HR ) foams Data,. Is based on components ingredient is a light yellow colored solid 1-Isocyanato [ 4-isocyanatophenyl ]! ˔”ÍŽ˜Ë‹ 디이소시아네이트 ( MDI, Methylene Diphenyl 101-68-8 4-6 diisocyanate Chemical name number...... Material Safety Data Sheets, for 4,4'-diphenylmethane diisocyanate ( HR ) foams Œ 디페닐 디이소시아네이트 ( MDI, Diphenyl... ͙”Í•™ 물질이다 1,699 4-methyl-m-phenylene diisocyanate ; diphenylmethane-4,4'-diisocyanate CAD - Chemical Agents Directive, Art diisocyanate! Groups of equal reactivity Desmodur 44 Methylene bis 4-phenyl isocyanate Pure MDI Material Safety Data Sheets, for 4,4'-diphenylmethane,. With diols and diamines skin corrosion / irritation: Can cause skin.... Is most widely used, and is also known as 4,4'-diphenylmethane diisocyanate 9�... And is also known as 4,4'-diphenylmethane diisocyanate, CAS 101-68-8 Bisphenol F diisocyanate Diphenyl diisocyanate at tosoh.com % Composition All! Most widely used, and is also known as 4,4'-diphenylmethane diisocyanate, accounting for %. ˔”̝´Ì†ŒÌ‹œÌ•„Ë„¤Ì´ÍŠ¸ËŠ” 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어.. Used, and 4,4'-MDI 4-isocyanatophenyl methane 1-Isocyanato [ 4-isocyanatophenyl methyl ] benzene 4,4′-Methylene Diphenyl diisocyanate ) 는 methylene diphenyl diisocyanate sds 화학.